This volume IFIP AICT 693 constitutes the refereed proceedings of the 10th IFIP International Workshop on Artificial Intelligence for Knowledge Management, AI4KMES 2023, from September 30th – October 1st, 2023, held in Krakow, Poland. The 15 full papers presented together with 2 short papers were carefully reviewed and selected from 49 submissions. The accepted papers covered a large scope of topics related to sustainability in various contexts such as smart cities, agriculture, energy and gas production and distribution, industry, management and biodiversity.